In alkali basaltic rocks scarcely appear accessory minerals such as zircon and corundum. The origin of these mostly gem stone like mega-crystals is unknown and controversial. However, if zircon crystals present they are important tools to clarify petrogenetic questions of the host melts. Host magmas of the zircon mega-crystals are normally SiO2 under saturated such as basanites and nephelinites.
In several localities we could observe some zircon mega-crystals and in a quarry in Saxony (eastern Germany) we collected 36 crystals up to 15 mm in size in situ from the basanitic rock. Zircons occur in agglutinates of lower crater facies of a scoria cone. The related lava flows are almost free of zircons and their Zr contents reaches up to 900 ppm. There is a good correlation between Ar/Ar data of the basanites (30 to 31 Ma) and the zircon U/Pb data which show ages about 30.5 Ma.
A further known locality of zircon mega-crystals is the so called Seufzergründel placer in Elbsandsteingebirge / Saxon Switzerland (eastern Germany). There are observed zircon mega-crystals up to 9 mm in size. Their host rock is a lapilli bearing volcanic breccia, implying here a polyphase explosive volcanism. The age data of zircons have various values; while the Pb/Pb crystallization-ages range by 54±6 Ma the U/Pb dating gets about 35 Ma.
Furthermore zircon mega-crystals were sampled from placers and residual soil of basanitic and nephelinitic as well as phonolitic rocks from different localities via heavy mineral separation techniques. The crystals show an intensive magmatic corrosion in alkalibasaltic rocks (including nephelinites), while zircons out of phonolites are mostly euhedral.
Thus the zircon mega-crystals were carried by alkali basaltic magmas but were not in equilibrium with these melts. Basaltic host rocks of the mega-crystals are developed of primitive mantle melts, implying a short residence time for zircons in the melt. The solution rates of zircon in such melts are possibly high which could be seen in the intense magmatic corrosion. Therefore zircon mega-crystals occur mostly in pyroclastic rocks and are scarce or absent in massive lava flows. The latter have a much longer cooling time.
Another possibility for enrichment of mega-crystals in pyroclastic rocks should be that the ascending bubbles in the vent carry away the solid parts, like xenocrystals or phenocrystals of the magma column. This could be the reason for lacking of in situ proofs of zircons in massive basalts.
The age data of the zircons in relation to that of the host rocks imply a cogenetic development of both.