The Repository for Radioactive Waste in Novi Han, Lozen Mountain (Bulgaria), dates from the early 1960s. In the present study, the complex geoenvironmental setting of the repository site was analysed from the viewpoint of assessment of potential radionuclide migration from the repository to the geosphere. Thus, components of the mass transport field were elaborated as a part of a conceptual model. In connection with this, a detailed characterization of the subsurface, especially of the vadose zone around the repository, was performed. The fractions of sand, silt and clay based on the grain-size distribution curves of samples from the different hydrogeological units gathered on the site of RAW-Novi Han were implemented in the ROSETTA program, and the respective hydraulic parameters were determined. As a result, the entire vadose zone was hydraulically determined.
The most representative subsurface section of the Famennian carbonate succession from the Moesian Platform in Bulgaria occurs in the R-2 Preslavtsi well. Nine microfacies types (MFTs 1–9) have been distinguished and described in the intraclastic and peloidal limestone unit and the organogenic limestone unit. They are grouped in four microfacies associations: 1) protected shallow subtidal (lagoon) (MFT 1, bioclastic-peloidal packstone/grainstone; and MFT 2, oncoidal wackestone); 2) wave-dominated shallow subtidal (MFT 3, intraclastic-peloidal grainstone and rudstone; MFT 4, oncoidal rudstone; MFT 5, peloidal-bioclastic packstone and grainstone); 3) reef (MFT 6, solenoporacean-calcimicrobial-stromatoporoid boundstone; MFT 7, crinoid-stromatoporoid floatstone); and 4) open-marine (MFT 8, bioclastic wackestone/packstone with intraclasts and peloids; and MFT 9, bioclastic wackestone and packstone). The carbonate deposits are interpreted as formed in various shallow- to open-marine environments at or above the fair-weather wave base (MFTs 1–7) and below it (MFTs 8 and 9). Most of the described microfacies are comparable with Wilson’s (1975) Standard Microfacies Types.
Plastic soil-cement is a type of soil stabilization used for the treatment of natural soil to improve its engineering properties. It is a hardened material prepared by mixing soil and Portland cement at a water content higher than optimum, usually near the liquid limit, without compaction at optimum water content to maximum dry density. In Bulgaria, this soil stabilization technique has been applied in foundation works in collapsible loess ground in order to replace a part of the collapsible layer, to increase the bearing capacity of the soil base and/or to isolate the geoenvironment from migration of pollutants.
The aim of the current paper is to examine the effect of the clay content of the loess soil on the strength and permeability of plastic loess-cement. Results from the investigation indicate that the mechanical and hydraulic properties of the plastic loess-cement highly depend on the presence of clay fraction.
The glass beads from the Dren-Delyan necropolis are found in burial complexes dated as from the end of the 6th century BC until the first half of the 4th century BC. The purpose of this study is to obtain data on the chemical composition of the glass and the technology of its production. LA-ICP-MS and SEM-EDS analyses were conducted.
The analysed glass beads are classified as a low-magnesium type (LMG), and only one of the samples is determined as high-magnesium glass (HMG). The yellow colour of the glass is due to crystals of lead antimonate incorporated into the glass matrix. The green colour of the beads is a result of interaction of added copper and lead in the glass mixture, in presence of iron and chromium. Dark blue samples are coloured by additives with cobalt, copper and lower iron content. Light blue colouration of opaque glass beads is due to high copper content, along with the presence of iron. The colouring agent of a transparent light blue bead is FeO in amount up to 0.25 wt%. The brown colour is associated with high iron content. Two different opacifiers were used for the production of opaque glass beads – antimony and tin, either individually or together. The decolourising agent is antimony without the involvement of manganese. Based on the results of the studied glass beads, we assume at least four types of raw material mixtures for their production. Comparison of the obtained results and published data about similar ancient glass findings was made.
Calpionellid study has provided new evidence of early and late Tithonian age of the top of the Gintsi Formation, and of late Tithonian and early Berriasian age of the Glozhene Formation in the Yavorets section (Western Balkan Mts, Bulgaria). The calpionellid Chitinoidella, Praetintinnopsella, Crassicollaria, and Calpionella zones have been documented in successive order. Three calcareous dinocyst zones – Colomisphaera tenuis, Colomisphaera fortis and Stomiosphaerina proxima, have been determined in this lower Tithonian to lower Berriasian interval. From the base upwards, the following microfacies have been recognized: Saccocoma (Gintsi Formation, lower and upper Tithonian), Globochaete alpina, and calpionellid (Glozhene Formation, upper Tithonian and lower Berriasian). The base of the Berriasian has been traced at the explosion of the uniformly shaped spherical variety of Calpionella alpina. Evolutionary lineages of species of the genus Calpionella are discussed, as well as the vertical distributions and abundance peaks of crassicollarians. The calpionellid zones described herein are correlated with coeval zonations from the Western, Central and Eastern Tethyan domains. The regional correlation with previously studied sections of Tithonian/Berriasian pelagic carbonates in the Western Balkan Mts revealed a transition to hemipelagic deposition of the limestone-marl succession of the Salash Formation and/or sandstone accumulation during the middle to late Berriasian (Elliptica and Simplex calpionellid subzones) due to unstable conditions of the sedimentary environment. From the west to the east in the Western Balkan Unit (i.e., from the Rosomač section in eastern Serbia to the Sarbenitsa, Bov and Yavorets sections in the Iskar River Valley area), there is a trend of slight progressive deepening of the basin. This is manifested in the occurrence of redeposited shallow-carbonate-platform microfossils in the west to greater thickenesses of the Gintsi and Glozhene formations and occurrence of sandstone channel deposits in the east.
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