Geochemical behaviour of K, Na, Li, Rb and Cs has been studied in coals, coaly shales and mineral interlayers from some Bulgarian coal deposits and manifestations. The elements show the following major trends in their distribution: 1. The higher the coal rank, the higher the elements' contents. This tendency is well pronounced for Cs and Jess so for K, Na, Li and Rb. Recalculated to ash, however, the Na content is higher in lignites than in brown and black coals; 2. Sorption ash carries and concentrates Na, and terrigenous ash is a carrier of K, Na, Li, Rb and Cs; 3. Na is typomorphic element in 8 of the deposits studied, Li in 6, and Cs in 2 of them; 4. With the exception of Na, the separate coal lithotypes do not concentrate alkaline elements; 5. The elements are bound with both the inorganic and the organic coal matter. K, Rb, Li and Cs occur mostly as Meinorg· Low ash coal in most of the deposits is dominated by Naorg and in some cases by Liorg as well; 6. The higher Na content in low-ash coals is explained with its greater supply in a dissolved state. Seawater was the source of Na in the Sozopol deposit and, to a lesser extent, in the Burgas and Dobrudza deposits as well. In the other deposits a Na source may have been the terrigenous material supplied into the peat bog from which Na is more readily extracted than the other alkaline elements. The contents of alkaline elements in coals and in coaly shales are positively correlated. Syngenetic and epigenetic hydrothermal fluids as well as underground water are an other sources of alkaline elements.
Amphibolites from subintrusive and bedded bodies belonging to the Lukovica Formation oi the Rhodope Supergroup in the Northern-Rhodope Anticline are fully characterized chemically and are divided into three groups: high-aluminum, high-iron and high-chromium amphibolites. Their petrological features and major element composition as well as the contents and distribution patterns of trace elements are found to resemble closely those of the basic magmatic rocks of tholeiitic character.
The Virini-Pessani-Dadia area, NE of Alexandroupolis, W. Thrace, is made up of metamorphic rocks and in a major extent of Tertiary volcanic and sedimentary rocks. In the volcano-sedimentary association fine grained sandstones alternating with thin bedded pelites are overlain by mafic and felsic volcanics of Eocene-Oligocene age. These are intruded by quartz-feldspar porphyries. Felsic volcanics, the majority of which are of dacitic-rhyodacitic composition, comprise pyroclastic flow and fall deposits and lava flows and domes. All petrological and geochemical data indicate that the Eocene lavas are of andesitic composition and show characteristics of orogenic volcanic series of continental margins rather than of island arcs. Two types of mineralization can be distinguished in the explored area: a) Stratabound Zn-Pb-Cu semimassive mineralization occurring in a series of calcareous sandstones, which close to their contacts with felsic porphyries are propylitized and b) Epigendic fracture-filling Pb-Zn-Cu mineralization in epidote and chlorite-bearing sandstones. The low areal extent of the propylitized sandstones and the absence of any indication for the existence of massive ore at depth, are considered unlikely that the clastic sequence of the studied area is favourable to be the host of economic polymetallic ores.
The age of the monzonitic phase of Vitosa Pluton is determined by Rb-Sr whole-rock isochron on 8 samples as 91 ± 10 Ma, the initial 87Sr/ 86Sr ratio being 0.704. Therefore, the pluton was co-eval with the Upper Cretaceous (Turonian - Lower Senonian) volcanic activity of the Srednogorie Zone, and with the granitoid intrusions in the west part of the Rhodope Massif. It is supposed that subduction along the east margin of Vardar Zone, extension and island-arc formation in the Srednogorie Zone, and thickening in parts of Rhodope Massif created magma hearths at different depths of the crust and in the upper mantle during the Late Cretaceous.
The Priabonian-Oligocene magmatism in the Eastern Rhodope Mts. took place during an interval of 11-12 Ma (37-25.5 Ma). Fauna-dated Priabonian and Oligocene sediments are interbedded by lava flows (dated 37-35 Ma and 34-30 Ma, respectively) which corresponds to the age of the Priabonian-Oiigocene boundary as proposed by O d i n (34 ±1/2 Ma) and C a v e I i e r & P o m e r o I (35.7 ±0,4). The youngest, subvolcanic dike swarms are intruded at the Lower-Upper Oligocene boundary (28-25.5 Ma). Small hypabyssal intrusions are found to be contemporaneous with the volcanic activity as a whole. Three of them are dated 31.5-33 Ma.
N. P. Ruskova. Textural and mineralogical features of Paleogene sands in Northeast Bulgaria. The studies concern the sandy sediments of the Paleogene in Northeast Bulgaria which outcrop in a relatively persistent stratigraphic level of Lower Eocene age along the scarps of Momino, Frangen and Provadia Plateau. Two main lithological varieties occur - yellowish fine-grained sands to silts and white fine- to medium-grained sands. The first (along with a packet of white or grey-white sands) form the base of the section and arc related to Beloslav Formation, and the white coarser-grained sands (Dikilitas Formation) occur with a gradual transition in a higher stratigraphic level. Both types show characteristic texturaI parameters: the yellowish sands of Beloslav Formation are slightly clayey and not well sorted, gradually become purer upwards and in the packet of white sands with wide lateral and vertical distribution the textural parameters (σ1 0.5 to 0.9) indicate practically everywhere excellent sorting and normal distribution. The sands of Dikilitas Formation are more variable, locally cross- bedded (in Provadia Plateau), with rapidly changing textural parameters, relatively bad sorting (σ1 over 1), in places bimodal. In mineralogical respect the sands are monotonous, practically monomineral quartz or slightly oligomictic sands. The heavy fraction (below I %) consisting of stable accessory minerals, kyanite, magnetite (and its martitized varieties), epidote minerals and rarely amphibole, indicates mixed supply in which metamorphic, volcanomagmatic and mainly recyclic components take part. Typomorphic are kyanite, related probably to the metamorphic complex of North Dobdrudža, unstable epidote varieties, amphibole and magnetite - to the East Srednogorie zone, and garnet along with the main quartz amount - to the slightly cemented oltgomictic sandstones of Santonian age in Northeast Bulgaria.
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